2-[(E)-2-Hydroxy-3-methoxybenzylidene]-N-methylhydrazinecarbothioamide
نویسندگان
چکیده
In the crystal structure of the title compound, C11H15N3O2S, mol-ecules are linked by pairs of N-H⋯O and O-H⋯S hydrogen, forming inversion dimers. These dimers are linked by N-H⋯S hydrogen bonds, forming double-stranded chains propagating along the b-axis direction. The two C atoms of the end chain of the mol-ecule are disordered over two sets os sites [occupancy ratio 0.574 (9):0.426 (9)].
منابع مشابه
2-[1-(2-Hydroxy-6-methoxyphenyl)ethylidene]-N-methylhydrazinecarbothioamide acetonitrile monosolvate
In the title compound, C11H15N3O2S·C2H3N, the dihedral angle between the benzene ring and the mean plane of the hydrazinecarbothio-amide group is 75.1 (2)°. In the crystal, the main mol-ecule is linked to the solvent mol-ecule by a weak N-H⋯N hydrogen bond while O-H⋯S hydrogen bonds link the mol-ecules into columns along [100].
متن کامل(E)-2-[(E)-3-(Hydroxyimino)butan-2-ylidene]-N-methylhydrazinecarbothioamide
In the title compound, C(6)H(12)N(4)OS, an intra-molecular N-H⋯N hydrogen-bond is present giving rise to an S(5) ring motif. In the crystal, double-stranded chains propagating along [10[Formula: see text]] are formed via pairs of O-H⋯S and N-H⋯S hydrogen bonds. The chains are further stabilized by C-H⋯S interactions.
متن کامل(N 1 E,N 2 E)-N 1,N 2-Bis(4-hexyloxy-3-methoxybenzylidene)ethane-1,2-diamine
The title compound, C(30)H(44)N(2)O(4), was obtained from the dimerization of 4-hexyl-oxyvanillin with ethyl-enediamine in 95% methanol solution. It adopts a trans configuration with respect to the C=N bond and possesses a crystallographically imposed centre of symmetry.
متن کاملN′-(5-Bromo-2-methoxybenzylidene)-3-hydroxybenzohydrazide methanol hemisolvate
The asymmetric unit of the title compound, C(15)H(13)BrN(2)O(3)·0.5CH(3)OH, contains two Schiff base mol-ecules and a methanol mol-ecule of crystallization. The dihedral angles between the benzene rings in the two mol-ecules are 23.8 (2) and 18.6 (2)°. In the crystal structure, mol-ecules are linked through inter-molecular N-H⋯O, O-H⋯O and O-H⋯N hydrogen bonds, forming a three-dimensional network.
متن کاملBis{2-[3-(hydroxyimino-κN)butan-2-ylidene]-N-methylhydrazinecarbothioamide-κ2 N 2,S}nickel(II) dichloride
The asymmetric unit of the title compound, [Ni(C(6)H(12)N(4)OS)(2)]Cl(2), contains two independent Ni(II) complex cations and four chloride anions. Each Ni(II) ion is six-coordinated in a distorted octa-hedral geometry by four N atoms from the two imine and two oxime groups and two S atoms from the thione group. In the crystal, the cations and anions are linked through N-H⋯Cl and O-H⋯Cl hydroge...
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عنوان ژورنال:
دوره 69 شماره
صفحات -
تاریخ انتشار 2013